Download PDF by R.K. Saxena: Biology of Physical Science

By R.K. Saxena

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In view of these coefficients, the charge transfer band assignment can be approximated by a transfer of a base electron, nb' to the iodine 0'* orbital.

1 RELATIONSHIP OF POTENTIAL ENERGY CURVES TO ELECTRONIC SPECTRA An understanding of electronic absorption spectroscopy requires consideration of three additional principles: 1. 2 Morse curves for a ground and excited state of a diatomic molecule. showing vibrational probability functions. 'Vvil/ ' as dotted lines. have time to change position appreciably. This statement is referred to as the Franck-Condon principle. Since the electronic transition is rapid, the molecule will find itself with the same molecular on figuration and vibrational kinetic energy in the excited state that it had in the ground state at the moment of absorption of the photon.

The integral fy(x) dx represents the area under the curve. Since y(x) is positive in one quadrant and negative in the other, the area from +a to -a or from +00 to ~ is zero. Now, plot a function y(x) such that y is symmetric in x. This function is called "even" and does have AI symmetry, because it is unchanged by any of the operations of the symmetry group to which the function belongs. This can be shown by carrying out the symmetry operations of the C 2u point. The integral does not vanish. The shaded area gives the value for the integral fa ydx for y = X2, and it is seen not to cancel to zero.

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